Electron self-exchange activation parameters of diethyl sulfide and tetrahydrothiophene
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چکیده
منابع مشابه
Electron self-exchange activation parameters of diethyl sulfide and tetrahydrothiophene
Electron transfer between the title compounds and their radical cations, which were generated by photoinduced electron transfer from the sulfides to excited 2,4,6-triphenylpyrylium cations, was investigated by time-resolved measurements of chemically induced dynamic nuclear polarization (CIDNP) in acetonitrile. The strongly negative activation entropies provide evidence for an associative-disso...
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ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2013
ISSN: 1860-5397
DOI: 10.3762/bjoc.9.164